The extraordinary mechanical properties of carbon nanotubes (CNTs) have generated strong research interest in their possible use in reinforced composite materials. So far, different
studies using carbon-nanotube reinforcements in polymer composites have reported only small improvements in the bulk mechanical properties compared with traditional fiber-reinforced
composites. Through a novel approach, researchers have created a CNT-based composite material that exhibits significant improvements in fracture performance and structural damping.
The reason the use of CNTs in composites for structural applications has been disappointing is due to issues such as dispersion, alignment, and interfacial strength. A collaborative
research effort between the University of Hawaii and the Rensselaer Polytechnic Institute demonstrates an unexplored yet big opportunity for CNTs in composites. The researchers use CNTs
to influence and increase the 3D composite interlaminar properties, using unique reinforced laminae with carbon-nanotube forests grown on cloth fibers present in adjacent plies.
The findings of the research group, led by Professor Mehrdad Ghasemi Nejhad, director of the Hawaii Nanotechnology Laboratory at the University of Hawaii, and Professor Pulickel Ajayan at
Rensselaer were published in the May 7, 2006 online edition of Nature Materials (Multifunctional composites using reinforced laminae with carbon-nanotube forests).
In this work, we address major issues in composite materials, as well as nanocomposite materials, using the incredible multifunctional capabilities of CNTs Vinod Veedu, lead author of the
paper, explained to Nanowerk. They are very strong, highly conductive and have good damping properties. We explored all these possibilities when we incorporated nanotubes into composites
through a novel manufacturing method.
Nanotubes are a very versatile material with absolutely fascinating physical properties, all the way from ballistic conduction to really interesting mechanical behavior, but there are
major issues in introducing them to a polymer to make a nanocomposite material says Ajayan.
The 3-D nanocomposite materials that they introduced, address these issues and they could be well called a revolutionary material.
As reported in the Nature Materials article, the researchers demonstrate a novel approach in grafting well aligned forest of carbon nanotubes on silicon carbide ceramic fiber cloths. The
fiber cloths were then infiltrated with a high temperature polymer and then stacked on each other with the carbon nanotubes sandwiched in between the layers. The composites thus
manufactured were cured in a high temperature furnace.
Having carbon nanotube Velcro-like fasteners go in the through-thickness direction essentially would ensure the mechanical properties required in that direction says Ghasemi-Nejhad.
A series of tests showed that the new 3-D nanocomposite material exhibits four times better fracture performance and five-fold increase in their ability to dissipate energy by structural
damping in comparison to the original ceramic composites without nanotubes forests. The new nanocomposite material has three times better dimensional stability compared to the base
material without CNTs. This could well be the most preferred composite structure for the future structural applications, the researchers say.
Now, the most interesting fact here is that the new 3-D nanocomposite material that we introduced not only improves structural mechanical properties by several folds, but at the same time
they impart multifunctionality to the same structure says Veedu. We demonstrated that the novel 3-D nanocomposite performs much better in terms of thermal and electrical conductivities as
well.
Previous studies in correcting the through-thickness weakness of traditional fiber-reinforced composites were hampered by various issues, starting with the complexity of manufacturing
itself.
Our findings apply a major concept called hierarchical manufacturing, in which we start from a nano manufacturing process to build up a structural composite material. So this is exclusive
hierarchical composite manufacturing process Veedu comments.
The possibilities offered by this new composite material are intriguing. Just by looking at the aerospace, automotive or marine industries shows how large the market for modern composites
already is. The concept introduced by the researchers in Hawaii and New York could be used to make better composite structural materials in these and other areas, leading to
high-performance composites with superior mechanical, thermal, electrical and damping properties.
I believe future composite materials will not only have purely structural aspects, but they increasingly will be multifunctional as well says Veedu, and CNT-reinforced nanocomposite
materials will play an important role in this.
By Michael Berger, Copyright 2006 Nanowerk LLC